The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Peroxy radicals / Hydroxy-,methoxyalkylperoxy / HOC(CH3)2CH2O2 / Boyd(1996)_300K_220-270nm

DATAFILE: HOC(CH3)2CH2O2_Boyd(1996)_300K_220-270nm.txt
NAME: 2-hydroxy-2,2-dimethyl-1-ethylperoxy radical
FORMULA: HOC(CH3)2CH2O2
AUTHOR(YEAR): Boyd(1996)
T: 300K
λ: 220-270nm
BIBLIOGRAPHY: A.A. Boyd, R. Lesclaux, M.E. Jenkin, and T.J. Wallington, "A spectroscopic, kinetic, and product study of the (CH3)2C(OH)CH2O2 radical self-reaction and reaction with HO2", J. Phys. Chem. 100, 6594-6603 (1996); DOI: 10.1021/jp953292c
COMMENTS: A flash photolysis technique was used to measure the UV absorption spectrum of the peroxy radical formed in the (CH3)3COH/Cl/O2 reaction system

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